Refineries and Processes

Refineries and Processes

Petroleum refineries are industrial facilities that process crude oil into more usable products, such as gasoline, diesel fuel, kerosene, and liquefied petroleum gas (LPG)& (LNG). Natural gas refineries process raw natural gas to remove impurities and produce pipeline-quality dry natural gas. Both types of refineries are complex facilities that use a variety of processes to transform raw materials into finished products.  

#LPG: is primarily composed of propane and butane. #LNG: is mainly composed of methane.

Comparison chart of LPG and LNG features: Composition, liquefaction temperature, storage, and uses from refineries. LPG: Propane/butane, -40°C, pressurized tanks for heating. LNG: Methane, -160°C, cryogenic tanks for industrial use.
Comparison chart of LPG and LNG features: Composition, liquefaction temperature, storage, and uses from refineries. LPG: Propane/butane, -40°C, pressurized tanks for heating. LNG: Methane, -160°C, cryogenic tanks for industrial use.

Petroleum Refining Processes

The refining process for crude oil typically begins with the separation of the crude into different fractions by distillation. This is done by heating the crude oil and collecting the vapors that condense at different temperatures. The lightest fractions, such as gasoline and kerosene, have the lowest boiling points and are collected first. The heavier fractions, such as diesel fuel and lubricating oil, have higher boiling points and are collected later.  

After the crude oil has been distilled, the different fractions are further processed to remove impurities and improve their quality. This may involve a variety of processes, such as:

  • Cracking: Breaking down large hydrocarbon molecules into smaller ones to increase the yield of gasoline and other light products.  
  • Alkylation: Combining small hydrocarbon molecules into larger ones to improve the octane rating of gasoline.  
  • Isomerization: Rearranging the atoms in a hydrocarbon molecule to improve the quality of gasoline and other products.  
  • Treating: Removing impurities, such as sulfur, nitrogen, and oxygen, from the different fractions.  

Natural Gas Refining Processes

Natural gas refining involves removing impurities, such as water, carbon dioxide, and hydrogen sulfide, from raw natural gas. This is typically done through processes such as:  

  • Absorption: Using a liquid solvent to absorb the impurities.
  • Adsorption: Using a solid material to adsorb the impurities.  
  • Cryogenic separation: Cooling the natural gas to very low temperatures to separate the different components.  

API 936

API 936 is a standard developed by the American Petroleum Institute (API) that provides guidelines for the installation quality control of monolithic refractory linings in refineries. Refractory linings are used to protect equipment from high temperatures and corrosive materials. API 936 helps to ensure that refractory linings are installed correctly and will perform as intended.  

Environmental Impact

Both petroleum and natural gas refineries can have a significant impact on the environment. They can release air pollutants, such as sulfur dioxide and nitrogen oxides, which can contribute to acid rain and smog. They can also release water pollutants, such as oil and grease, which can contaminate waterways. Refineries can also be a source of noise pollution.  

There are a number of ways to reduce the environmental impact of refineries. One way is to use cleaner fuels, such as natural gas. Another way is to use more efficient processes. Refineries can also be designed to minimize their emissions of air and water pollutants.  

Refineries play an important role in the global economy. They provide the fuels and other products that we need to power our homes, businesses, and transportation systems. Refineries are also a major source of employment.  

Process UnitPrimary PurposeCatalyst UsedTypical Operating Temperature (°C)Typical Operating Pressure (bar)Main ProductsByproducts/ResidueRefractory Types
Crude Distillation Unit (CDU)Separate crude oil into different fractions based on boiling pointNone350-4001-2Gases, LPG, naphtha, kerosene, diesel, atmospheric residueAtmospheric residueFireclay, insulating castables
Vacuum Distillation Unit (VDU)Further separate atmospheric residue into lighter fractionsNone400-4500.1-0.5Vacuum gas oil, lubricating oil, vacuum residueVacuum residueFireclay, high-alumina, insulating castables
Fluid Catalytic Cracking Unit (FCCU)Convert heavy fractions into gasoline and dieselZeolite500-5501-2Gasoline, diesel, LPG, olefinsCatalyst cokeHigh-alumina, silica-alumina, refractory concrete
Fluid CokerConvert heavy fractions into petroleum cokeNone500-6002-5Petroleum coke, gas oil, naphthaPetroleum cokeHigh-alumina, fireclay, insulating castables
HydrocrackerConvert heavy fractions into lighter, higher-value productsNoble metal catalyst350-450100-200Gasoline, diesel, kerosene, LPGMinimal residueHigh-alumina, dense castables
Catalytic ReformerIncrease the octane number of naphthaPlatinum or rhenium on alumina450-55010-35High-octane gasoline, hydrogenMinimal residueHigh-alumina, dense castables with low iron content
Hydrotreating UnitRemove sulfur and other contaminants from petroleum fractionsCobalt-molybdenum or nickel-molybdenum catalyst300-40020-70Desulfurized productsMinimal residueFireclay, high-alumina, chrome-based refractories (for high-temperature applications)
Alkylation UnitCombine isobutane and light olefins to produce high-octane gasolineSulfuric acid or hydrofluoric acid10-207-14Alkylate (high-octane gasoline)Minimal residueAcid-resistant bricks, carbon bricks, fluorocarbon linings (for HF)
Isomerization UnitConvert straight-chain paraffins to branched-chain isomers to increase octane numberPlatinum on chlorinated alumina120-18020-30Isomerate (high-octane gasoline)Minimal residueLow-cement castables, high-alumina
Visbreaking Unit /Thermal CrackingReduce the viscosity of heavy residuesNone450-5005-10Lighter fuel oil, gas oilMinimal residueFireclay, high-alumina
Delayed Coking UnitProduce petroleum coke from heavy residuesNone450-5002-7Petroleum coke, gas oil, naphthaPetroleum cokeHigh-alumina, fireclay, insulating castables
Solvent Deasphalting UnitRemove asphaltenes from heavy residuesPropane or butane50-8030-50Deasphalted oil (DAO)AsphaltenesStainless steel, low-temperature castables
Lube Oil Processing UnitsProduce lubricating oils from vacuum gas oilVarious catalysts and processesVariesVariesLubricating oils, waxes-Fireclay, high-alumina, insulating castables
Amine Treating Unit / Sulfur Recovery UnitRemove hydrogen sulfide (H2S) from gas streams and convert it to elemental sulfurAmine solution / Claus process catalystVariesVariesClean gas streams / Elemental sulfurMinimal residueAcid-resistant bricks and linings, specialized refractories for sulfur recovery
Sour Water StripperRemove H2S and ammonia from wastewaterSteam stripping100-1201-2Clean waterMinimal residueCorrosion-resistant materials, often with specialized coatings
Gasification UnitConvert hydrocarbons into synthesis gas (carbon monoxide and hydrogen)Nickel or other metal catalysts900-150020-70Synthesis gasAshHigh-alumina, chrome-magnesite, silicon carbide

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